Symmetry preservation in a new noncentrosymmetric lattice comprised of acentric POM clusters residing in bowls of Cs(+)-based half SOD β-cage.
نویسندگان
چکیده
In light of ever growing interests in noncentrosymmetric materials, a fascinating reticular chemistry is illustrated via the structure of a new family of solids where the acentric symmetry of the well-known [V(4+)(14)As(3+)(8)O(42)Cl](5-) POM cluster is manifested through the network construction of counter cations featuring slabs of Cs(+)-based half SOD β-cages.
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ورودعنوان ژورنال:
- Chemical communications
دوره 48 11 شماره
صفحات -
تاریخ انتشار 2012